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Yields a consistent prediction for the fe-porphyrin complex. Pair-density functional theory predicts spin-state ordering in iron complexes with. If the crystal field splitting parameter (δ) is small because of weak-bonding ligands, then the pairing energy will be larger and the complex will be high-spin. Due to paired electrons, complex called low spin or spin paired complex. Geometry of complexes -. Geometry of complexes depends on. Crystal field designation for an outer orbital complex; all t2g and eg orbitals are singly occupied before any pairing occurs. Dinuclear sco molecules can adopt three different spin-pair states: a fully. In order for this to make sense, there must be some sort of energy benefit to having paired spins for our cyanide complex. That is, the energy level difference
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1 0 0 example: what is the magnetic susceptibility of [cof6]3-,. Spin pairing energy refers to the energy associated with paired electrons. Nitrite is a strong-field ligand, so the complex will be low spin. [6] take, for example, an octahedron in which six ligands,. A semiquinone spin-coupled to the reduced 2fe2s cluster. What happens when the electron pairing energy is larger than the octahedral field splitting energy? choose one answer. The result is a low-spin complex,
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